HCID 21710574, compound → HCID 21710568, compound

HRID 651044Notes

Reaction equation

HRID 651044 reaction equation
[CH2:1]([C:8]([OH:15])([CH2:11][CH2:12][CH2:13][CH3:14])[CH2:9][OH:10])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[H][H]>CO>[CH:2]1([CH2:1][C:8]([OH:15])([CH2:11][CH2:12][CH2:13][CH3:14])[CH2:9][OH:10])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1

Participants

4

Reactant 2

HCID 21710574HCID 21710574, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 21710568HCID 21710568, compoundYield 92%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A solution of the product from Example 19B (1.07 g, 5.19 mmol) was reduced using hydrogen gas at 4 atm in the presence of Rh/alumina in methanol to provide 1.02 g (92%) of the title compound.

Sources & evidence

ORD record
ord-70bfd030a2584546bb7a157fd65ea689
Source dataset
uspto-grants-2001_08
Patent number
US06277871B1

Reaction notes

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