HRID65169

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID13547656

未命名化合物

结构：CC(CC(Sc1cc(C(C)(C)C)c(O)c(C(C)(C)C)c1)Sc1cc(C(C)(C)C)c(O)c(C(C)(C)C)c1)Sc1cc(C(C)(C)C)c(O)c(C(C)(C)C)c1

HCID13643570

未命名化合物

HCID13643574

未命名化合物

PRODUCTS

生成物

结构：Cc1cc(SC(C)CC(Sc2cc(C)c(O)c(C(C)(C)C)c2)Sc2cc(C)c(O)c(C(C)(C)C)c2)cc(C(C)(C)C)c1O

HCID13643575

未命名化合物

PROCEDURE

实验过程

The instant compound named above is made in an analogous manner to the compound of Example 3 by reacting a one molar proportion of reactant (a) with two molar proportions of 2-tert-butyl-6-methyl-4-mercaptophenol. After recrystallization from a solvent mixture of 12:1 heptane:toluene, the compound is isolated as white crystals melting at 65°-69° C.

WORKUP

后处理

customAfter recrystallization
additionfrom a solvent mixture of 12:1 heptane

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-469bd49a40de46099c814524dd4398c9
来源数据集: uspto-grants-1986_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04612341
来源说明: uspto-grants-1986_09

反应 SMILES

[C:1]([C:5]1[CH:6]=[C:7]([S:16][CH:17]([S:37][C:38]2[CH:43]=[C:42]([C:44](C)(C)C)[C:41]([OH:48])=[C:40]([C:49]([CH3:52])([CH3:51])[CH3:50])[CH:39]=2)[CH2:18][CH:19]([S:21][C:22]2[CH:27]=[C:26]([C:28](C)(C)C)[C:25]([OH:32])=[C:24]([C:33]([CH3:36])([CH3:35])[CH3:34])[CH:23]=2)[CH3:20])[CH:8]=[C:9]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:10]=1[OH:11])(C)(C)C.C(C1C=C(SC(C)CC=O)C=C(C)C=1O)(C)(C)C.C(C1C=C(S)C=C(C)C=1O)(C)(C)C>>[C:49]([C:40]1[CH:39]=[C:38]([S:37][CH:17]([S:16][C:7]2[CH:6]=[C:5]([CH3:1])[C:10]([OH:11])=[C:9]([C:12]([CH3:13])([CH3:15])[CH3:14])[CH:8]=2)[CH2:18][CH:19]([S:21][C:22]2[CH:27]=[C:26]([CH3:28])[C:25]([OH:32])=[C:24]([C:33]([CH3:34])([CH3:35])[CH3:36])[CH:23]=2)[CH3:20])[CH:43]=[C:42]([CH3:44])[C:41]=1[OH:48])([CH3:50])([CH3:51])[CH3:52]