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HRID65189

反应详情

EQUATION

反应方程式

HRID 65189 的结构方程式

REACTANTS

反应物

3
结构：N
HCID222

Ammonia gas

H3N

结构：C1CCNCC1
HCID8082

Piperidine

C5H11N

结构：CSC(=C[N+](=O)[O-])SC
HCID83623

1-Nitro-2,2-bis(methylthio)ethylene

C4H7NO2S2

PRODUCTS

生成物

1
结构：NC(=C[N+](=O)[O-])N1CCCCC1
HCID70447703

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClCC(Cl)(Cl)Cl
溶剂HCID12418

1,1,1,2-Tetrachloroethane

C2H2Cl4

PROCEDURE

实验过程

16.5 grams of 1,1-bis-(methylthio)-2-nitroethene are dissol ved under hot conditions in 100 ml of tetrachloroethane, 8.5 grams of piperidine are added, the mixture is heated under reflux for 2 hours, is then cooled and anhydrous gaseous ammonia is added until saturated.

WORKUP

后处理

  1. temperaturethe mixture is heated
  2. temperatureunder reflux for 2 hours
  3. temperatureis then cooled