HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrogen Peroxide → HCID 13911126, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrogen Peroxide | HCID 784 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | 25-Hydroxycholesta-1,4,6-trien-3-one | HCID 22797387 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 13911126 | HCID 13911126 | — |
Reaction Steps
The trienone from (a) (1.3 gms) in ethanol (50 mls) was treated with 10% aqueous potassium hydroxide (0.5 ml) and 30% aqueous H2O2 (3 ml). After storage overnight at room temperature, the solution was diluted with water and the solid product collected. Recrystallization from aqueous methanol gave the title compound which after one further crystallization had melting point 162°-163°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04670190 |
| Source dataset | uspto-grants-1987_06 |
| ORD ID | ord-c0d60886cd6b4abc8e6870ceca398957 |
| Source note | uspto-grants-1987_06 |