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HRID651948

反应详情

EQUATION

反应方程式

HRID 651948 的结构方程式

REACTANTS

反应物

3
结构：OO
HCID784

Hydrogen peroxide

H2O2

结构：[K+].[OH-]
HCID14797

Potassium hydroxide

HKO

结构：C[C@H](CCCC(C)(C)O)[C@H]1CC[C@H]2[C@@H]3C=CC4=CC(=O)C=C[C@]4(C)[C@H]3CC[C@]12C
HCID22797387

未命名化合物

PRODUCTS

生成物

1
结构：C[C@H](CCCC(C)(C)O)[C@H]1CC[C@H]2[C@@H]3C=CC4=CC(=O)[C@@H]5O[C@@H]5[C@]4(C)[C@H]3CC[C@]12C
HCID13911126

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CCO
溶剂HCID702

Ethanol

C2H6O

结构：O
溶剂HCID962

Water

H2O

PROCEDURE

实验过程

The trienone from (a) (1.3 gms) in ethanol (50 mls) was treated with 10% aqueous potassium hydroxide (0.5 ml) and 30% aqueous H2O2 (3 ml). After storage overnight at room temperature, the solution was diluted with water and the solid product collected. Recrystallization from aqueous methanol gave the title compound which after one further crystallization had melting point 162°-163°.

WORKUP

后处理

  1. customthe solid product collected
  2. customRecrystallization from aqueous methanol