Sodium Hydroxide → Sodium 4-[14-(trimethylsilyl)tetradecylamino]benzoate

HRID 652020Notes

Reaction equation

HRID 652020 reaction equation
[CH3:1][Si:2]([CH3:28])([CH3:27])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][NH:17][C:18]1[CH:26]=[CH:25][C:21]([C:22]([OH:24])=[O:23])=[CH:20][CH:19]=1.[OH-].[Na+:30]>C(O)C>[CH3:28][Si:2]([CH3:1])([CH3:27])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][NH:17][C:18]1[CH:19]=[CH:20][C:21]([C:22]([O-:24])=[O:23])=[CH:25][CH:26]=1.[Na+:30]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 138848624-[14-(Trimethylsilyl)tetradecylamino)benzoic acid

Product 1

HCID 23702177Sodium 4-[14-(trimethylsilyl)tetradecylamino]benzoate

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

To a stirred, hot solution of 4.5 g. 4-[14-(trimethylsilyl)tetradecylamino]benzoic acid in 150 ml. absolute ethanol was added 2.2 ml. 10N sodium hydroxide. The solution was cooled and the precipitate was filtered off and dried to yield a light yellow solid, m.p. 350°-355° C. dec.

Workup

  1. temperatureThe solution was cooled
  2. filtrationthe precipitate was filtered off
  3. customdried
  4. customto yield a light yellow solid, m.p. 350°-355° C. dec.

Sources & evidence

ORD record
ord-2645a447203f4c6596900cf4364ac758
Source dataset
uspto-grants-1987_06
Patent number
US04670421

Reaction notes

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