Trichloromethanesulfenyl chloride → HCID 86740550, compound

HRID 652122Notes

Reaction equation

HRID 652122 reaction equation
[Cl:1][C:2]([Cl:6])([Cl:5])[S:3]Cl.[F:7][C:8]([F:13])([F:12])[C:9]([OH:11])=[O:10].[NH2:14][CH2:15][CH:16]([Cl:24])[CH2:17]S(C(F)(F)F)=O.FC(F)(F)C(O)=[O:28].NCC(Cl)CS(Cl)(C(F)F)=O.FC(F)(F)C(O)=O.NCC(Cl)CS(Cl)(Cl)(CF)=O>>[F:7][C:8]([F:13])([F:12])[C:9]([OH:11])=[O:10].[NH2:14][CH2:15][CH:16]([Cl:24])[CH2:17][S:3]([C:2]([Cl:6])([Cl:5])[Cl:1])=[O:28]

Participants

5

Reactant 4

HCID 11666Trichloromethanesulfenyl chlorideHCID 86740551HCID 86740551, compoundHCID 131714452HCID 131714452, compoundHCID 178511095HCID 178511095, compound

Product 1

HCID 86740550HCID 86740550, compound

Procedure

Employing the procedure substantially as described in Example 4, but substituting for the trichloromethylsulfenyl chloride used in Step A thereof, an equimolecular amount of the sulfenyl chlorides of structure RSCl wherein R is F3C--, ClF2C--, and FCl2C--, there are produced respectively: 1-amino-2-chloro-3-(trifluoromethylsulfinyl)propane trifluoroacetic acid salt; 1-amino-2-chloro-3-(chlorodifluoromethylsulfinyl)propane trifluoroacetic acid salt; and 1-amino-2-chloro-3-(dichlorfluoromethylsulfinyl)propane trifluoroacetic acid salt.

Workup

  1. customare produced respectively

Sources & evidence

ORD record
ord-5e3fee360b17448683e3dd77b7642039
Source dataset
uspto-grants-1987_06
Patent number
US04670470

Reaction notes

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