Acetyl chloride → 4-Acetoxybiphenyl

HRID 652285Notes

Reaction equation

HRID 652285 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:4][CH:3]=1.[C:14](Cl)(=[O:16])[CH3:15].[Al+3].[Cl-].[Cl-].[Cl-]>>[C:14]([O:1][C:2]1[CH:3]=[CH:4][C:5]([C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:6][CH:7]=1)(=[O:16])[CH3:15]

Participants

4

Reactant 3

HCID 6367Acetyl chlorideHCID 71034-HydroxybiphenylHCID 6451240Aluminum(III) Chloride

Product 1

HCID 3460664-AcetoxybiphenylYield 94%

Procedure

When a mixture of 4-hydroxybiphenyl with acetyl chloride and AlCl3 in a molar ratio of 1:1:1 was reacted for 1 hr, only 4-acetoxybiphenyl ##STR66## was obtained in a yield of 94%.

Workup

  1. customwas reacted for 1 hr

Sources & evidence

ORD record
ord-f07e9179f0f448f5a9ccd7520fcf27e0
Source dataset
uspto-grants-1987_06
Patent number
US04670581

Reaction notes

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