4-Hydroxybenzaldehyde → HCID 309278, compound

HRID 652567Notes

Reaction equation

HRID 652567 reaction equation
[NH2:1][CH2:2]CS(O)(=O)=O.[C:8]1([CH3:16])[CH:13]=[CH:12][C:11]([CH:14]=O)=[CH:10][CH:9]=1.[NH2:17][CH2:18][C:19]([OH:21])=O.[OH:22]C1C=CC(C=O)=CC=1>>[CH3:16][C:8]1[CH:13]=[CH:12][C:11]([CH:14]=[C:18]2[NH:17][C:2](=[O:22])[NH:1][C:19]2=[O:21])=[CH:10][CH:9]=1

Participants

5

Reactant 4

HCID 1264-HydroxybenzaldehydeHCID 750GlycineHCID 1123TaurineHCID 77254-Methylbenzaldehyde

Product 1

HCID 309278HCID 309278, compound

Procedure

5-(p-Methylbenzylidene)-hydantoin was prepared in the same manner as in Example 4, except that 31.3 g (0.25 mol) of taurine and 60.0 g (0.50 mol) of p-tolualdehyde were used in lieu of glycine and p-hydroxybenzaldehyde, respectively. During the reaction, the pH of the reaction mixture was 9.8 to 9.6.

Workup

  1. customDuring the reaction

Sources & evidence

ORD record
ord-570b58f4dcdb49a49453d63146f5b2f5
Source dataset
uspto-grants-1987_06
Patent number
US04672127

Reaction notes

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