HuagongsheHuagongshe Chemistry Print Report · For research reference only
HCID 13765534, compound → HCID 13765536, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | HCID 13765534 | HCID 13765534 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Nickel | HCID 935 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 13765536 | HCID 13765536 | — |
Reaction Steps
10 g of the 3-methyl-1,1,3-tri(ethoxycarbonylamino)propane prepared in Example 3a are hydrogenated at 165° C. and 200 bar of hydrogen in a stirred autoclave with 3 g of Raney nickel and 100 ml of ethanol in the course of 15 hours. Complete converion gives 1-methyl-1,3-di(ethoxycarbonylamino)propane with a selectivity of 96%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04672137 |
| Source dataset | uspto-grants-1987_06 |
| ORD ID | ord-c63bdcc7717f412eb016703e1eb12519 |
| Source note | uspto-grants-1987_06 |