Methyl iodide → HCID 178503614, compound

HRID 653050Notes

Reaction equation

HRID 653050 reaction equation
[CH3:1][C:2]1[N:3]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[C:4]([S:7][CH3:8])=[N:5][N:6]=1.[CH3:15][I:16]>>[I-:16].[CH3:15][N+:6]1[N:5]=[C:4]([S:7][CH3:8])[N:3]([C:9]2[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=2)[C:2]=1[CH3:1]

Participants

3

Reactant 2

HCID 6328Methyl iodideHCID 11432464H-1,2,4-Triazole, 3-methyl-5-(methylthio)-4-phenyl-

Product 1

HCID 178503614HCID 178503614, compound

Procedure

Then, 10 g of 5 methyl-3-methylthio-4-phenyl-1,2,4-triazole thus obtained was mixed with 40 g of methyl iodide and the mixture was heat-refluxed for 4 hours to precipitate crystals, which were collected by filtration and recrystallized from ethanol to provide 1,5-dimethyl-3-methylthio-4-phenyl-1,2,4-triazolium iodide.

Workup

  1. temperaturethe mixture was heat-refluxed for 4 hours
  2. customto precipitate crystals, which
  3. filtrationwere collected by filtration
  4. customrecrystallized from ethanol

Sources & evidence

ORD record
ord-db64228d94d742c1923662bd00d1d4a0
Source dataset
uspto-grants-1987_06
Patent number
US04675276

Reaction notes

Loading…