Sulfuryl chloride → HCID 13382702, compound

HRID 653070Notes

Reaction equation

HRID 653070 reaction equation
[C:1]1([S:7][CH2:8][CH2:9][CH2:10][C:11]#[N:12])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.S(Cl)([Cl:16])(=O)=O>C(Cl)Cl>[Cl:16][CH:8]([S:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH2:9][CH2:10][C:11]#[N:12]

Participants

4

Reactant 2

HCID 24648Sulfuryl chlorideHCID 2715014-phenylsulfanylbutanenitrile

Product 1

HCID 13382702HCID 13382702, compoundYield 102.9%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

To a solution of 50 g (0.28 mole) of 4-phenylthiobutyronitrile in 200 ml of methylene chloride is added 40.5 g (0.3 mole) of sulfuryl chloride dropwise during a period of six hours. Stirring is continued overnight. Solvent and excess sulfuryl chloride is then evaporated under vacuum to give 61 g of a crude product. This material is used in the next experiment without further purification.

Workup

  1. customSolvent and excess sulfuryl chloride is then evaporated under vacuum

Sources & evidence

ORD record
ord-c47a004dd6284f2babbf9e21b936bd50
Source dataset
uspto-grants-1987_06
Patent number
US04675316

Reaction notes

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