Glutaric anhydride → Glutaric Acid

HRID 653084Notes

Reaction equation

HRID 653084 reaction equation
[C:1]1(=[O:8])[O:7][C:5](=[O:6])[CH2:4][CH2:3][CH2:2]1.[OH-:9].[Na+]>O.[N+]([O-])([O-])=O.[Ag+]>[C:1]([OH:7])(=[O:8])[CH2:2][CH2:3][CH2:4][C:5]([OH:9])=[O:6]

Participants

5

Reactant 2

HCID 7940Glutaric anhydrideHCID 14798Sodium Hydroxide

Product 1

HCID 743Glutaric Acid

Reagents, catalysts & solvents 2

HCID 24470Silver NitrateCatalystHCID 962WaterSolvent2×

Procedure

An 11.76 g portion of 97% glutaric anhydride was dissolved in a mixture of 40 ml of 5N sodium hydroxide and 200 ml of water. A solution of 33.8 g of silver nitrate in 100 ml of water was added, the suspension was stirred for 1 hour in the dark, then the solid was collected, washed with water and dried, giving 33.5 g of glutaric acid, disilver salt.

Workup

  1. customthe solid was collected
  2. washwashed with water
  3. customdried

Sources & evidence

ORD record
ord-f68795a711bc41268c5ebf6801c15282
Source dataset
uspto-grants-1987_06
Patent number
US04675336

Reaction notes

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