HCID 13070187, compound → HCID 19889136, compound

HRID 653593Notes

Reaction equation

HRID 653593 reaction equation
[CH:1]1[C:14]2[C:5](=[CH:6][C:7]3[C:12]([C:13]=2[CH2:15][CH:16]=[O:17])=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1.[CH3:18][Mg]I>CCOCC>[CH:11]1[C:12]2[C:7](=[CH:6][C:5]3[C:14]([C:13]=2[CH2:15][CH:16]([OH:17])[CH3:18])=[CH:1][CH:2]=[CH:3][CH:4]=3)[CH:8]=[CH:9][CH:10]=1

Participants

4

Reactant 2

HCID 13070187HCID 13070187, compoundHCID 178418373HCID 178418373, compound

Product 1

HCID 19889136HCID 19889136, compoundYield 89%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

9-anthrylacetaldehyde (1.1 g; 5 mmoles) was Soxhlet--extracted for a period of 6 hours in an ether solution (100 ml) of methylmagnesium iodide (30 mmoles; prepared from 0.72 g of magnesium). Work up as described above gave 1.05 g (89%) of 1-(9-anthryl)-2-propanol as pale yellow needle shaped crystals, mp 105°-107° C.

Sources & evidence

ORD record
ord-526e854b716442f18046fbb4ff1dc6f8
Source dataset
uspto-grants-1992_07
Patent number
US05128120

Reaction notes

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