Glycerol → HCID 131716512, compound

HRID 654001Notes

Reaction equation

HRID 654001 reaction equation
[OH:1][CH2:2][CH:3]([CH2:5][OH:6])[OH:4].[C:7]([OH:26])(=[O:25])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14]/[CH:15]=[CH:16]\[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].OP(O)(O)=O>O>[C:7]([OH:26])(=[O:25])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14]/[CH:15]=[CH:16]\[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24].[OH:1][CH2:2][CH:3]([CH2:5][OH:6])[OH:4].[OH:1][CH2:2][CH:3]([CH2:5][OH:6])[OH:4].[OH:1][CH2:2][CH:3]([CH2:5][OH:6])[OH:4]

Participants

5

Reactant 3

HCID 753GlycerolHCID 1004Phosphoric AcidHCID 445639Oleic Acid

Product 1

HCID 131716512HCID 131716512, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Conditions

Temperature
230 °C

Procedure

770 g of glycerine and 767 g of oleic acid were treated with catalyst prepared in a similar way as in Example 4. 4 g of Ca(OH)2 (dry) premixed with 26 g of water and 15 g of 25% H3PO4 premixed with 30 g of water were added at room temperature. The batch was heated to 230° C. under 23 inches of maximum vacuum in 2 hours time and reacted for another 3 hours. 240 g of total water was collected.

Workup

  1. customprepared in a similar way as in Example 4
  2. additionwere added at room temperature
  3. customreacted for another 3 hours
  4. custom240 g of total water was collected

Sources & evidence

ORD record
ord-189caeecaf694f89af3c9f942413fb2d
Source dataset
uspto-grants-1992_07
Patent number
US05130060

Reaction notes

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