Sucrose → Raffinose Oleate

HRID 65426Notes

Reaction equation

[CH2:1]([OH:34])[C@H:2]1[O:7][C@H:6]([O:8][CH2:9][C@H:10]2[O:15][C@H:14]([O:16][C@:17]3([CH2:26][OH:27])[O:21][C@H:20]([CH2:22][OH:23])[C@@H:19]([OH:24])[C@@H:18]3[OH:25])[C@H:13]([OH:28])[C@@H:12]([OH:29])[C@@H:11]2[OH:30])[C@H:5]([OH:31])[C@@H:4]([OH:32])[C@H:3]1[OH:33].[CH2:35](O)[C@H:36]1[O:41][C@H:40]([O:42][C@]2(CO)O[C@H](CO)[C@@H](O)[C@@H]2O)[C@H:39](O)[C@@H:38](O)[C@@H:37]1O>>[CH2:1]([OH:34])[C@H:2]1[O:7][C@H:6]([O:8][CH2:9][C@H:10]2[O:15][C@H:14]([O:16][C@:17]3([CH2:26][OH:27])[O:21][C@H:20]([CH2:22][OH:23])[C@@H:19]([OH:24])[C@@H:18]3[OH:25])[C@H:13]([OH:28])[C@@H:12]([OH:29])[C@@H:11]2[OH:30])[C@H:5]([OH:31])[C@@H:4]([OH:32])[C@H:3]1[OH:33].[C:40]([O-:41])(=[O:42])[CH2:39][CH2:38][CH2:37][CH2:36][CH2:35][CH2:1][CH2:2]/[CH:3]=[CH:4]\[CH2:5][CH2:6][CH2:22][CH2:20][CH2:19][CH2:18][CH2:17][CH3:26]

Participants

Reactant 2

HCID 5988Sucrose

HCID 439242Raffinose

Product 1

HCID 86741041Raffinose OleateYield 85.2%

Procedure

The procedure of Example 1 was repeated except that 10.08 g of raffinose was substituted for 3.4 g of sucrose. 6.65 g of raffinose oleate was obtained.

Sources & evidence

ORD record: ord-18c892d44946454b87745d85f30ded14
Source dataset: uspto-grants-1986_09
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04614718

Reaction notes

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