HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl formate → Diethyl alpha-formylglutarate Sodium Salt
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl formate | HCID 8025 | — |
| Reactant | Diethyl glutarate | HCID 13163 | — |
| Reactant | Sodium | HCID 5360545 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | Diethyl alpha-formylglutarate Sodium Salt | HCID 86635375 | — |
Reaction Steps
Prepared from diethyl glutarate and ethyl formate in the presence of sodium metal in diethyl ether according to the literature procedure (J. Bigs, P. Sykes, J. Chemical Society (1959), 1849-55). Obtained solid (28 g; 45%). LCMS (ES+) m/z 238 (MH+).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08071592B2 |
| Source dataset | uspto-grants-2011_12 |
| ORD ID | ord-af93b703aa5f4b30a1afeb89b79e868c |
| Source note | uspto-grants-2011_12 |