Ethanol → 1,3-Dimethyl-3-(ethoxycarbonylperoxy)butyl ethyl carbonate

HRID 65974Notes

Reaction equation

HRID 65974 reaction equation
Cl[C:2]([O:4][CH:5]([CH3:17])[CH2:6][C:7]([CH3:16])([O:9][O:10][C:11]([O:13][CH2:14][CH3:15])=[O:12])[CH3:8])=[O:3].C([OH:20])C.N1[CH:26]=[CH:25]C=CC=1>C(OCC)C>[C:2](=[O:20])([O:3][CH2:25][CH3:26])[O:4][CH:5]([CH3:17])[CH2:6][C:7]([CH3:16])([O:9][O:10][C:11]([O:13][CH2:14][CH3:15])=[O:12])[CH3:8]

Participants

5

Reactant 3

HCID 702EthanolHCID 1049PyridineHCID 233466131,3-Dimethyl-3(ethoxycarbonylperoxy)butyl chloroformate

Product 1

HCID 233466051,3-Dimethyl-3-(ethoxycarbonylperoxy)butyl ethyl carbonate

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent2×

Procedure

To a solution of 24.4 g. (0.0786 mole) of (86.4%) 1,3-dimethyl-3(ethoxycarbonylperoxy)butyl chloroformate in 100 ml of diethyl ether, cooled at 10°±1° C was added a solution of 4.6 g (0.1 mole) of ethanol and 7.9 g. (0.1 mole) of pyridine in 25 ml of diethyl ether over a period of 20 minutes.

Sources & evidence

ORD record
ord-41234ce8fa264851a247626055a69791
Source dataset
uspto-grants-1978_12
Patent number
US04129700

Reaction notes

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