m-Chloroperbenzoic acid → HCID 58116482, compound

HRID 661293Notes

Reaction equation

HRID 661293 reaction equation
[CH2:1]([O:3][C:4]1[N:8]=[C:7]([CH:9]2[CH2:14][CH:13]([C:15]3[CH:20]=[CH:19][C:18]([C:21]([F:24])([F:23])[F:22])=[CH:17][CH:16]=3)[CH2:12][N:11]([C:25]([N:27]3[CH2:32][CH2:31][S:30][CH2:29][CH2:28]3)=[O:26])[CH2:10]2)[O:6][N:5]=1)[CH3:2].ClC1C=CC=C(C(OO)=[O:41])C=1>>[CH2:1]([O:3][C:4]1[N:8]=[C:7]([CH:9]2[CH2:14][CH:13]([C:15]3[CH:20]=[CH:19][C:18]([C:21]([F:24])([F:22])[F:23])=[CH:17][CH:16]=3)[CH2:12][N:11]([C:25]([N:27]3[CH2:28][CH2:29][S:30](=[O:41])[CH2:31][CH2:32]3)=[O:26])[CH2:10]2)[O:6][N:5]=1)[CH3:2]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 58116538HCID 58116538, compound

Product 1

HCID 58116482HCID 58116482, compound

Procedure

65.0 mg (0.138 mmol) of the compound from Example 44 were reacted according to General Method 2 with 42.9 mg (0.124 mmol) of meta-chloroperbenzoic acid. Yield: 50.8 mg (72% of theory)

Sources & evidence

ORD record
ord-6bcb119a49bd49359af61ab901170de2
Source dataset
uspto-grants-2011_12
Patent number
US08084469B2

Reaction notes

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