Benzoyl chloride → HCID 20340702, compound

HRID 66181Notes

Reaction equation

HRID 66181 reaction equation
[O:1]([CH2:8][CH2:9][CH2:10][O:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:18](Cl)(=[O:25])[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1.[Cl-].[Al+3].[Cl-].[Cl-]>ClCCCl>[C:18]([C:5]1[CH:4]=[CH:3][C:2]([O:1][CH2:8][CH2:9][CH2:10][O:11][C:12]2[CH:13]=[CH:14][C:15]([C:18](=[O:25])[C:19]3[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=3)=[CH:16][CH:17]=2)=[CH:7][CH:6]=1)(=[O:25])[C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1

Participants

5

Reactant 3

HCID 7412Benzoyl chlorideHCID 136562Benzene, 1,1'-(1,3-propanediylbis(oxy))bis-HCID 6451240Aluminum(III) Chloride

Product 1

HCID 20340702HCID 20340702, compound

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

1,3-Diphenoxypropane (22.8 g), benzoyl chloride (31 g) and anhydrous aluminum chloride (33 g) are reacted in 1,2-dichloroethane (300 ml) for 18 hours at 70° to yield 33.4 g (77% of theory) of colorless crystals mp 146°-8°.

Sources & evidence

ORD record
ord-eab2928a1b0c4a11b830bcb5515c3726
Source dataset
uspto-grants-1978_12
Patent number
US04130664

Reaction notes

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