Dimethyl Sulfoxide → 2-(Methylsulfonyl)-4-(trifluoromethoxy)benzoic acid

HRID 662269Notes

Reaction equation

HRID 662269 reaction equation
[Br:1][c:2]1[c:3]([C:4](=[O:5])[OH:6])[cH:7][cH:8][c:9]([O:11][C:12]([F:13])([F:14])[F:15])[cH:10]1.[CH3:16][S:17](=[O:18])[O-:19].[CH3:25][S:26](=[O:27])[CH3:28].[Cu:23][I:24].[K+:22].[Na+:20].[OH-:21]>>[c:2]1([S:17]([CH3:16])(=[O:18])=[O:19])[c:3]([C:4](=[O:5])[OH:6])[cH:7][cH:8][c:9]([O:11][C:12]([F:13])([F:14])[F:15])[cH:10]1

Participants

8

Reactant 7

HCID 679Dimethyl SulfoxideHCID 813Potassium CationHCID 923Sodium ionHCID 961HydroxideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 3870744MethanesulfinateHCID 594474442-Bromo-4-(trifluoromethoxy)benzoic acid

Product 1

HCID 594473092-(Methylsulfonyl)-4-(trifluoromethoxy)benzoic acid

Sources & evidence

ORD record
ord-3ca0f85712744827b6b8bb72ba424777
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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