Acetate → Tert-butyl 3-[4-[9-bicyclo[3.3.1]nonanylidene-(4-hydroxyphenyl)methyl]phenyl]prop-2-enoate

HRID 667333Notes

Reaction equation

HRID 667333 reaction equation
[C:25]([CH:26]=[CH2:27])(=[O:28])[O:29][C:30]([CH3:31])([CH3:32])[CH3:33].[CH3:34][CH2:35][N:36]([CH2:37][CH3:38])[CH2:39][CH3:40].[CH3:50][C:51]#[N:52].[CH:1]12[CH2:2][CH2:3][CH2:4][CH:5]([CH2:6][CH2:7][CH2:8]1)[C:9]2=[C:10]([c:11]1[cH:12][cH:13][c:14]([OH:17])[cH:15][cH:16]1)[c:18]1[cH:19][cH:20][c:21]([Br:24])[cH:22][cH:23]1.[O-:42][C:43]([CH3:44])=[O:45].[O-:46][C:47]([CH3:48])=[O:49].[Pd+2:41]>>[CH:1]12[CH2:2][CH2:3][CH2:4][CH:5]([CH2:6][CH2:7][CH2:8]1)[C:9]2=[C:10]([c:11]1[cH:12][cH:13][c:14]([OH:17])[cH:15][cH:16]1)[c:18]1[cH:19][cH:20][c:21]([CH:27]=[CH:26][C:25](=[O:28])[O:29][C:30]([CH3:31])([CH3:32])[CH3:33])[cH:22][cH:23]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 6342AcetonitrileHCID 8471TriethylamineHCID 15458tert-Butyl acrylateHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 686546174-[Bicyclo[3.3.1]non-9-ylidene(4-bromophenyl)methyl]phenol

Product 1

HCID 68979556Tert-butyl 3-[4-[9-bicyclo[3.3.1]nonanylidene-(4-hydroxyphenyl)methyl]phenyl]prop-2-enoate

Sources & evidence

ORD record
ord-87c29dd3fb1246bf927732b40610e063
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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