Potassium Cation → 5-Bromo-1-(4-methylbenzene-1-sulfonyl)-1H-indole

HRID 672856Notes

Reaction equation

HRID 672856 reaction equation
[Br:1][c:2]1[cH:3][c:4]2[cH:5][cH:6][nH:7][c:8]2[cH:9][cH:10]1.[CH2:29]([N+:30]([CH2:31][CH2:32][CH2:33][CH3:34])([CH2:35][CH2:36][CH2:37][CH3:38])[CH2:39][CH2:40][CH2:41][CH3:42])[CH2:43][CH2:44][CH3:45].[CH3:46][c:47]1[cH:48][cH:49][cH:50][cH:51][cH:52]1.[K+:23].[OH-:22].[S:24]([O-:25])([OH:26])(=[O:27])=[O:28].[c:11]1([CH3:21])[cH:12][cH:13][c:14]([S:17](=[O:18])(=[O:19])[Cl:20])[cH:15][cH:16]1>>[Br:1][c:2]1[cH:3][c:4]2[cH:5][cH:6][n:7]([S:17]([c:14]3[cH:13][cH:12][c:11]([CH3:21])[cH:16][cH:15]3)(=[O:18])=[O:19])[c:8]2[cH:9][cH:10]1

Participants

8

Reactant 7

HCID 813Potassium CationHCID 961HydroxideHCID 1140TolueneHCID 73974-Toluenesulfonyl chlorideHCID 16028TetrabutylammoniumHCID 249055-BromoindoleHCID 61778Sulfate, hydrogen

Product 1

HCID 119546185-Bromo-1-(4-methylbenzene-1-sulfonyl)-1H-indole

Sources & evidence

ORD record
ord-61f547f41e07474887ec9ef93684e271
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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