Hydroxide → Tert-butyl 3-(3-methoxy-3-oxoprop-1-enyl)-2,2-dimethylcyclopropane-1-carboxylate

HRID 673509Notes

Reaction equation

HRID 673509 reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[CH:8]1[C:9]([CH3:17])([CH3:18])[CH:10]1[C:11]#[C:12][C:13](=[O:14])[O:15][CH3:16].[CH3:29][CH2:30][O:31][C:32](=[O:33])[CH3:34].[OH-:35].[OH-:37].[Pd+2:36].[cH:19]1[cH:20][c:21]2[c:22]([n:23][cH:24][cH:25][cH:26]2)[cH:27][cH:28]1>>[C:1]([CH3:2])([CH3:3])([CH3:4])[O:5][C:6](=[O:7])[CH:8]1[C:9]([CH3:17])([CH3:18])[CH:10]1[CH:11]=[CH:12][C:13](=[O:14])[O:15][CH3:16]

Participants

6

Reactant 5

HCID 961Hydroxide2×HCID 7047QuinolineHCID 8857Ethyl AcetateHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 12807745Tert-butyl 3-(3-methoxy-3-oxoprop-1-ynyl)-2,2-dimethylcyclopropane-1-carboxylate

Product 1

HCID 76457714Tert-butyl 3-(3-methoxy-3-oxoprop-1-enyl)-2,2-dimethylcyclopropane-1-carboxylate

Sources & evidence

ORD record
ord-c161b620bbe047c1adf4b68d81a49504
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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