Sodium ion → 4-[8-Chloro-5,6-Dihydro-4-(Phenylmethylthio)-11H-Benzo[5,6]Cyclohepta[1,2-b]Pyridin-11-Ylidene]-1-(3-Pyridinylacetyl)-Piperidine

HRID 674913Notes

Reaction equation

HRID 674913 reaction equation
[CH2:35]([c:36]1[cH:37][cH:38][cH:39][cH:40][cH:41]1)[SH:42].[Cl:1][c:2]1[c:3]2[c:4]([n:5][cH:6][cH:7]1)[C:8](=[C:18]1[CH2:19][CH2:20][N:21]([C:24]([CH2:25][c:26]3[cH:27][n:28][cH:29][cH:30][cH:31]3)=[O:32])[CH2:22][CH2:23]1)[c:9]1[c:10]([cH:13][c:14]([Cl:17])[cH:15][cH:16]1)[CH2:11][CH2:12]2.[H-:33].[Na+:34].[O:43]=[CH:44][N:45]([CH3:46])[CH3:47]>>[c:2]1([S:42][CH2:35][c:36]2[cH:37][cH:38][cH:39][cH:40][cH:41]2)[c:3]2[c:4]([n:5][cH:6][cH:7]1)[C:8](=[C:18]1[CH2:19][CH2:20][N:21]([C:24]([CH2:25][c:26]3[cH:27][n:28][cH:29][cH:30][cH:31]3)=[O:32])[CH2:22][CH2:23]1)[c:9]1[c:10]([cH:13][c:14]([Cl:17])[cH:15][cH:16]1)[CH2:11][CH2:12]2

Participants

6

Reactant 5

HCID 923Sodium ionHCID 6228DimethylformamideHCID 7509Benzyl mercaptanHCID 166653HydrideHCID 226219554-[4,8-Dichloro-5,6-Dihydro-11H-Benzo[5,6]Cyclohepta[1,2-b]Pyridin-11-Ylidene]-1-(3-Pyridinylacetyl)-Piperidine

Product 1

HCID 226219804-[8-Chloro-5,6-Dihydro-4-(Phenylmethylthio)-11H-Benzo[5,6]Cyclohepta[1,2-b]Pyridin-11-Ylidene]-1-(3-Pyridinylacetyl)-Piperidine

Sources & evidence

ORD record
ord-cef695d4971142ff9ef9f4b21c6fcdf6
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

Loading…