Tetrahydrofuran → Phosphorane, (1-methylethylidene)triphenyl-

HRID 675933Notes

Reaction equation

HRID 675933 reaction equation
[CH2:1]([Li:2])[CH2:3][CH2:4][CH3:5].[CH3:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34].[CH:7]([CH3:8])([CH3:9])[P+:10]([c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1)([c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1)[c:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1.[I-:6].[O:35]1[CH2:36][CH2:37][CH2:38][CH2:39]1>>[C:7]([CH3:8])([CH3:9])=[P:10]([c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1)([c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1)[c:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1

Participants

6

Reactant 5

HCID 8028TetrahydrofuranHCID 8058HexaneHCID 30165Iodide IonHCID 2723784IsopropyltriphenylphosphoniumHCID 178418339Butyllithium

Product 1

HCID 140117Phosphorane, (1-methylethylidene)triphenyl-

Sources & evidence

ORD record
ord-552399be07ba4f07829738aa0bd42872
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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