HuagongsheHuagongshe Chemistry Print Report · For research reference only
Phosphorus oxide (P4O10) → 4-(4-Chloro-3-chlorosulfonylphenyl)-3-methyl-2-phenylimino-4-thiazoline hydrobromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Phosphorus oxide (P4O10) | HCID 14812 | — |
| Reactant | 4-(4-Chloro-3-chlorosulfonylphenyl)-3-methyl-2-phenyliminothiazolidin-4-ol hydrobromide | HCID 20527317 | — |
| Solvent | Water | HCID 962 | — |
| Product | 4-(4-Chloro-3-chlorosulfonylphenyl)-3-methyl-2-phenylimino-4-thiazoline hydrobromide | HCID 20527346 | — |
Reaction Steps
2.5 g (50 mmoles) of 4-(4-chloro-3-chlorosulfonylphenyl)-3-methyl-2-phenyliminothiazolidin-4-ol hydrobromide are heated rapidly in a jacket, which has been preheated to 220° C., in vacuo (0.1 mm Hg) over phosphorus pentoxide. The substance melts with foaming, as a result of the elimination of water, and solidifies immediately after the end of the reaction, with recrystallization. Slightly green colored crystals; melting point 264° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04346088 |
| Source dataset | uspto-grants-1982_08 |
| ORD ID | ord-d5bdb40cd2b5457ca0efdf1021e3579c |
| Source note | uspto-grants-1982_08 |