HRID686068

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID813

Potassium cation

K+

HCID962

Water

H2O

HCID1140

Toluene

C7H8

HCID8058

n-Hexane

C6H14

HCID8857

Ethyl acetate

C4H8O2

HCID74506

Triphenylmethylphosphonium

C19H18P+

HCID4574913

未命名化合物

结构：CC(C)(C)[Si](C)(C)OC1CC(C=O)N(Cc2ccccc2)C1

HCID19971475

未命名化合物

PRODUCTS

生成物

结构：C=CC1CC(O[Si](C)(C)C(C)(C)C)CN1Cc1ccccc1

HCID19971412

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-31132d0130cc459a9edad872a485179f
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (3/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (3/10)

反应 SMILES

[Br-:36].[CH2:7]([c:8]1[cH:9][cH:10][cH:11][cH:12][cH:13]1)[N:14]1[CH:15]([CH:27]=[O:28])[CH2:16][CH:17]([O:19][Si:20]([CH3:21])([CH3:22])[C:23]([CH3:24])([CH3:25])[CH3:26])[CH2:18]1.[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH3:30][CH2:31][O:32][C:33](=[O:34])[CH3:35].[CH3:37][P+:38]([c:39]1[cH:40][cH:41][cH:42][cH:43][cH:44]1)([c:45]1[cH:46][cH:47][cH:48][cH:49][cH:50]1)[c:51]1[cH:52][cH:53][cH:54][cH:55][cH:56]1.[CH3:57][c:58]1[cH:59][cH:60][cH:61][cH:62][cH:63]1.[CH3:64][CH2:65][CH2:66][CH2:67][CH2:68][CH3:69].[K+:6].[OH2:29]>>[CH2:1]=[CH:27][CH:15]1[N:14]([CH2:7][c:8]2[cH:9][cH:10][cH:11][cH:12][cH:13]2)[CH2:18][CH:17]([O:19][Si:20]([CH3:21])([CH3:22])[C:23]([CH3:24])([CH3:25])[CH3:26])[CH2:16]1