Sodium ion → 3-Cyclopentyl-2-(4-ethylsulfanyl-phenyl)-acrylic acid ethyl ester

HRID 692063Notes

Reaction equation

HRID 692063 reaction equation
[CH2:37]([CH3:38])[O:39][C:40]([C:41](=[O:42])[c:43]1[cH:44][cH:45][c:46]([S:49][CH2:50][CH3:51])[cH:47][cH:48]1)=[O:52].[CH3:27][Si:28]([N-:29][Si:30]([CH3:31])([CH3:32])[CH3:33])([CH3:34])[CH3:35].[CH:2]1([CH2:7][P+:8]([c:9]2[cH:10][cH:11][cH:12][cH:13][cH:14]2)([c:15]2[cH:16][cH:17][cH:18][cH:19][cH:20]2)[c:21]2[cH:22][cH:23][cH:24][cH:25][cH:26]2)[CH2:3][CH2:4][CH2:5][CH2:6]1.[I-:1].[Na+:36].[O:53]1[CH2:54][CH2:55][CH2:56][CH2:57]1>>[CH:2]1([CH:7]=[C:41]([C:40]([O:39][CH2:37][CH3:38])=[O:52])[c:43]2[cH:44][cH:45][c:46]([S:49][CH2:50][CH3:51])[cH:47][cH:48]2)[CH2:3][CH2:4][CH2:5][CH2:6]1

Participants

7

Reactant 6

HCID 923Sodium ionHCID 8028TetrahydrofuranHCID 30165Iodide IonHCID 3280088Npc316347HCID 22315320Cyclopentylmethyl(triphenyl)phosphaniumHCID 24722266Ethyl 4-(ethylthio)benzoylformate

Product 1

HCID 537336713-Cyclopentyl-2-(4-ethylsulfanyl-phenyl)-acrylic acid ethyl ester

Sources & evidence

ORD record
ord-9bc4785d6c674c1d8c767e350fd04f89
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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