Bromide ion → 3-Bromo-5-(bromomethyl)pyridine

HRID 694971Notes

Reaction equation

HRID 694971 reaction equation
[Br-:27].[Br:1][c:2]1[cH:3][c:4]([CH2:8][OH:9])[cH:5][n:6][cH:7]1.[CH2:29]([Cl:30])[Cl:31].[K+:21].[K+:22].[Li+:28].[O-:23][C:24]([O-:25])=[O:26].[S:16]([Cl:17])([CH3:18])(=[O:19])=[O:20].[cH:10]1[cH:11][cH:12][n:13][cH:14][cH:15]1>>[Br:1][c:2]1[cH:3][c:4]([CH2:8][Br:27])[cH:5][n:6][cH:7]1

Participants

9

Reactant 8

HCID 259Bromide ionHCID 813Potassium Cation2×HCID 1049PyridineHCID 6344DichloromethaneHCID 19660Carbonate IonHCID 28486Lithium ionHCID 31297Methanesulfonyl chlorideHCID 2784733(5-Bromo-3-pyridinyl)methanol

Product 1

HCID 149329483-Bromo-5-(bromomethyl)pyridine

Sources & evidence

ORD record
ord-e8d1b50b096c4b9d909587b8a0009af2
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

Loading…