Dimethyl Sulfoxide → 5-(2-Oxiranyl)-1,3-benzodioxole

HRID 697943Notes

Reaction equation

HRID 697943 reaction equation
[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH3:29][S:30](=[O:31])[CH3:32].[CH3:8][S+:9]([CH3:10])[CH3:11].[CH:12](=[O:13])[c:14]1[cH:15][cH:16][c:17]2[c:21]([cH:22]1)[O:20][CH2:19][O:18]2.[I-:7].[K+:6].[O:24]1[CH2:25][CH2:26][CH2:27][CH2:28]1.[OH2:23]>>[CH2:1]1[CH:12]([c:14]2[cH:15][cH:16][c:17]3[c:21]([cH:22]2)[O:20][CH2:19][O:18]3)[O:13]1

Participants

9

Reactant 8

HCID 679Dimethyl SulfoxideHCID 813Potassium CationHCID 962WaterHCID 1147TrimethylsulfoniumHCID 8028TetrahydrofuranHCID 8438PiperonalHCID 30165Iodide IonHCID 45749132-Methylpropan-2-olate

Product 1

HCID 108990185-(2-Oxiranyl)-1,3-benzodioxole

Sources & evidence

ORD record
ord-685b5a3d01524a9ba9df74c74db2b52e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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