Dichloromethane → (5-Bromo-pent-2-ynyloxy)-tert-butyl-diphenyl-silane

HRID 700392Notes

Reaction equation

[Br:25][C:26]([Br:27])([Br:28])[Br:29].[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][C:8]#[C:9][CH2:10][CH2:11][OH:12])([c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1)[c:19]1[cH:20][cH:21][cH:22][cH:23][cH:24]1.[Cl:49][CH2:50][Cl:51].[c:30]1([P:31]([c:32]2[cH:33][cH:34][cH:35][cH:36][cH:37]2)[c:38]2[cH:39][cH:40][cH:41][cH:42][cH:43]2)[cH:44][cH:45][cH:46][cH:47][cH:48]1>>[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][C:8]#[C:9][CH2:10][CH2:11][Br:25])([c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1)[c:19]1[cH:20][cH:21][cH:22][cH:23][cH:24]1

Participants

Reactant 4

HCID 6344Dichloromethane

HCID 11205Carbon tetrabromide

HCID 11776Triphenylphosphine

HCID 142175645-{[tert-Butyl(diphenyl)silyl]oxy}pent-3-yn-1-ol

Product 1

HCID 57829248(5-Bromo-pent-2-ynyloxy)-tert-butyl-diphenyl-silane

Sources & evidence

ORD record: ord-98025b840b15412aa5fd99d208fee886
Source dataset: Training data from https://doi.org/10.1039/C8SC04228D (3/10)
DOI: 10.1039/C8SC04228D

Reaction notes

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