Dimethylformamide → ethyl 1-methyl-5-nitro-3-phenyl-1H-indole-2-carboxylate

HRID 700629Notes

Reaction equation

HRID 700629 reaction equation
[C:26](=[O:27])([O-:28])[O-:29].[Cs+:30].[Cs+:31].[I:24][CH3:25].[N+:1](=[O:2])([O-:3])[c:4]1[cH:5][c:6]2[c:7](-[c:18]3[cH:19][cH:20][cH:21][cH:22][cH:23]3)[c:8]([C:13](=[O:14])[O:15][CH2:16][CH3:17])[nH:9][c:10]2[cH:11][cH:12]1.[O:32]=[CH:33][N:34]([CH3:35])[CH3:36]>>[N+:1](=[O:2])([O-:3])[c:4]1[cH:5][c:6]2[c:7](-[c:18]3[cH:19][cH:20][cH:21][cH:22][cH:23]3)[c:8]([C:13](=[O:14])[O:15][CH2:16][CH3:17])[n:9]([CH3:26])[c:10]2[cH:11][cH:12]1

Participants

6

Reactant 5

HCID 6228DimethylformamideHCID 6328Methyl iodideHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 741309ethyl 5-nitro-3-phenyl-1H-indole-2-carboxylate

Product 1

HCID 69231753ethyl 1-methyl-5-nitro-3-phenyl-1H-indole-2-carboxylate

Sources & evidence

ORD record
ord-461ad86cbd394ce1aff20db353f54c87
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (3/10)

Reaction notes

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