Methanesulfonyl chloride → HCID 14536793, compound

HRID 703146Notes

Reaction equation

HRID 703146 reaction equation
O[CH2:2][CH2:3][S:4][CH2:5][CH2:6][CH2:7][C:8]([CH3:15])([CH3:14])[C:9]([O:11][CH2:12][CH3:13])=[O:10].CS(Cl)(=O)=O.[Br-:21].[Li+]>>[Br:21][CH2:2][CH2:3][S:4][CH2:5][CH2:6][CH2:7][C:8]([CH3:15])([CH3:14])[C:9]([O:11][CH2:12][CH3:13])=[O:10]

Participants

4

Reactant 3

HCID 31297Methanesulfonyl chlorideHCID 82050Lithium BromideHCID 14536792HCID 14536792, compound

Product 1

HCID 14536793HCID 14536793, compoundYield 62%

Procedure

from ethyl 8-hydroxy-2,2-dimethyl-6-thiaoctanoate and methanesulphonyl chloride and subsequent reaction of the resultant methanesulphonyloxy compound with lithium bromide. Yield 62% of theory; colourless oil;

Sources & evidence

ORD record
ord-ab58c70d9f544308a603182a5c08d7de
Source dataset
uspto-grants-1991_01
Patent number
US04981873

Reaction notes

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