Acetone → n-Propyl-2,2-dimethyl-1,3-benzodioxol

HRID 704006Notes

Reaction equation

HRID 704006 reaction equation
[CH2:1]([C:4]1[CH:5]=[C:6]([OH:11])[C:7](=[CH:9][CH:10]=1)O)[CH2:2][CH3:3].[CH3:12][C:13]([CH3:15])=[O:14].O.C1(C)C=CC(S(O)(=O)=O)=CC=1>C1C=CC=CC=1>[CH2:1]([C:4]1[C:5]2[O:14][C:13]([CH3:15])([CH3:12])[O:11][C:6]=2[CH:7]=[CH:9][CH:10]=1)[CH2:2][CH3:3]

Participants

5

Reactant 3

HCID 180AcetoneHCID 976384-Propyl-1,2-benzenediolHCID 521998p-Toluenesulfonic acid monohydrate

Product 1

HCID 57166457n-Propyl-2,2-dimethyl-1,3-benzodioxol

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

The same procedures as described in Example 10 were carried out by using a mixture of 7.61 g (50 mM) of 4-n-propylcatechol, 15 ml of acetone, 30 mg of p-toluenesulfonic acid monohydrate and 15 ml of benzene. 5 n-Propyl-2,2-dimethyl-1,3-benzodioxol was obtained in the yield of 9.13 g (47 mM) as colorless transparent liquid having a boiling point of 82°-87° C./3 mmHg.

Sources & evidence

ORD record
ord-1fbb50898417489abff812e62b076e90
Source dataset
uspto-grants-1991_01
Patent number
US04985458

Reaction notes

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