Cyanuric chloride → 1,3,5-Triazine, 2,4,6-tris(1-azetidinyl)-

HRID 704114Notes

Reaction equation

HRID 704114 reaction equation
[NH:1]1[CH2:4][CH2:3][CH2:2]1.[N:5]1[C:12](Cl)=[N:11][C:9](Cl)=[N:8][C:6]=1Cl>O>[N:1]1([C:6]2[N:8]=[C:9]([N:1]3[CH2:4][CH2:3][CH2:2]3)[N:11]=[C:12]([N:1]3[CH2:4][CH2:3][CH2:2]3)[N:5]=2)[CH2:4][CH2:3][CH2:2]1

Participants

4

Reactant 2

HCID 7954Cyanuric chlorideHCID 10422Azetidine

Product 1

HCID 1520761,3,5-Triazine, 2,4,6-tris(1-azetidinyl)-Yield 78%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Compound LXXVI was prepared after the method of Schaefer (J Am Chem Soc (1955) 77 p592B). The hydrochloride salt of azetidine was reacted with cyanuric chloride in water to give compound LXXVI as a white solid (yield 78%) having a melting point of 225°-238° C. The 1Hnmr of this compound indicated that its identity was correct and that its purity was adequate for subsequent reactions without further purification.

Workup

  1. customCompound LXXVI was prepared after the method of Schaefer (J Am Chem Soc (1955) 77 p592B)

Sources & evidence

ORD record
ord-5e35f850284549238e6e160ccc3f5f5b
Source dataset
uspto-grants-1991_01
Patent number
US04985584

Reaction notes

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