Sodium Chloride → HCID 20075700, compound

HRID 704289Notes

Reaction equation

HRID 704289 reaction equation
[CH2:1]([SH:3])[CH3:2].[CH2:4]([CH:9]1[CH2:14][CH2:13][CH:12]([CH:15]2[CH2:20][CH2:19][C:18]([CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])(O)[CH2:17][CH2:16]2)[CH2:11][CH2:10]1)[CH2:5][CH2:6][CH2:7][CH3:8].C(OC(=O)C)(=O)C.Cl(O)(=O)(=O)=O.[Cl-].[Na+]>C(O)(=O)C>[CH2:4]([CH:9]1[CH2:14][CH2:13][CH:12]([CH:15]2[CH2:20][CH2:19][C:18]([CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])([S:3][CH2:1][CH3:2])[CH2:17][CH2:16]2)[CH2:11][CH2:10]1)[CH2:5][CH2:6][CH2:7][CH3:8]

Participants

7

Reactant 5

HCID 5234Sodium ChlorideHCID 6343EthanethiolHCID 7918Acetic AnhydrideHCID 24247Perchloric AcidHCID 20076205HCID 20076205, compound

Product 1

HCID 20075700HCID 20075700, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent2×

Procedure

7.2 g of ethanethiol and 35 g of 4-pentyl-4'heptyl-4'-hydroxybicyclohexane in 70 ml of glacial acetic acid are added dropwise to a mixture of 30 ml of glacial acetic acid, 11.1 g of acetic anhydride and 7 g of 72% aqueous perchloric acid solution at -20°. The mixture is stirred at room temperature for 24 hours, poured into 250 ml of saturated sodium chloride solution, extracted with petroleum ether and worked up in the customary manner. 4-Pentyl-4'-heptyl-4'-ethylthiobicyclohexane is obtained.

Workup

  1. extractionextracted with petroleum ether

Sources & evidence

ORD record
ord-0469ec7d524d4eeabe5d4242ea5d8e13
Source dataset
uspto-grants-1991_01
Patent number
US04985583

Reaction notes

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