HuagongsheHuagongshe Chemistry Print Report · For research reference only
Selenium Dioxide → 4-Bromo-2,1,3-benzoselenadiazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Selenium Dioxide | HCID 24007 | — |
| Reactant | 3-Bromobenzene-1,2-diamine | HCID 12489839 | — |
| Solvent | Ethanol | HCID 702 | — |
| Solvent | Water | HCID 962 | — |
| Product | 4-Bromo-2,1,3-benzoselenadiazole | HCID 71150192 | — |
Reaction Steps
The specific preparation is described as follows: refluxing 3-bromo-1,2-diaminobenzene in ethanol solution, then adding into selenium dioxide dissolved in hot water, after that, refluxing for 2 hours. The precipitation is recrystallized with ethyl acetate after being filtered to get 4-bromo-2,1,3-benzoselenadiazole finally.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08822634B2 |
| Source dataset | uspto-grants-2014_09 |
| ORD ID | ord-7150227821db4b80bc2389f71b850cfe |
| Source note | uspto-grants-2014_09 |