Ferrous Chloride → (2,6-Dimethyl-phenyl)-(1-{6-[1-(2-isopropyl-phenylimino)-ethyl]-pyridin-2-yl}ethylidene)-amine iron (II) chloride

HRID 707729Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 707729
[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([CH3:8])[C:3]=1[N:9]=[C:10]([C:12]1[CH:17]=[CH:16][CH:15]=[C:14]([C:18](=[N:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][C:22]=2[CH:27]([CH3:29])[CH3:28])[CH3:19])[N:13]=1)[CH3:11].[Fe:30]([Cl:32])[Cl:31]>C1COCC1>[Fe:30]([Cl:32])[Cl:31].[CH3:1][C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([CH3:8])[C:3]=1[N:9]=[C:10]([C:12]1[CH:17]=[CH:16][CH:15]=[C:14]([C:18](=[N:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][C:22]=2[CH:27]([CH3:29])[CH3:28])[CH3:19])[N:13]=1)[CH3:11]

Komponenten

4

Edukt 2

HCID 24458Ferrous ChlorideHCID 86674238(2,6-Dimethyl-phenyl)-(1-{6-[1-(2-isopropyl-phenylimino)-ethyl]-pyridin-2-yl}ethylidene)-amine

Produkt 1

HCID 131732192(2,6-Dimethyl-phenyl)-(1-{6-[1-(2-isopropyl-phenylimino)-ethyl]-pyridin-2-yl}ethylidene)-amine iron (II) chloride

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 8028TetrahydrofuranLösungsmittel

Versuchsvorschrift

(2,6-Dimethyl-phenyl)-(1-{6-[1-(2-isopropyl-phenylimino)-ethyl]-pyridin-2-yl}-ethylidene)-amine 8 (1.0 g, 0.0026 mol) was added in one portion to the suspension of 0.31 g (0.0025 mol) of iron (II) chloride in 50 ml of THF at ambient temperature in nitrogen glove box. The reaction mixture was stirred for 12 h. The resultant blue solid was filtered and washed by 50 ml of pentanes three times and dried under 1-mm vacuum overnight. The yield of (2,6-dimethyl-phenyl)-(1-{6-[1-(2-isopropyl-phenylimino)-ethyl]-pyridin-2-yl}-ethylidene)-amine iron (II) chloride 10 was 1.06 g (85%).

Aufarbeitung

  1. filtrationThe resultant blue solid was filtered
  2. washwashed by 50 ml of pentanes three times
  3. customdried under 1-mm vacuum overnight

Quellen und Nachweise

ORD-Eintrag
ord-0dc31b9555594a119776687999a9d6a5
Quelldatensatz
uspto-grants-2015_11
Patentnummer
US09175104B2

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