Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 2-Bromopyridine | HCID 7973 | — |
| Reactant | [(Trichloromethyl)sulfanyl]benzene | HCID 23273522 | — |
| Solvent | Formamide | HCID 713 | — |
| Product | HCID 817760 | HCID 817760 | 81% |
Reaction Steps
A solution of phenyl(trichloromethyl)sulfane (0.25 g, 1.099 mmol) in formamide (16.40 ml), was degassed with nitrogen and treated with 2-bromopyridine (0.115 ml, 1.209 mmol). The reaction solution was heated at 75° C. overnight. Gas Chromatography-Mass Spectrometry (GCMS) indicates a yield of 81% of 2-(phenylthio)pyridine, and a 7% byproduct of disulfide.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US09181270B2 |
|---|
| Source dataset | uspto-grants-2015_11 |
|---|
| ORD ID | ord-d013315b44224a8b9d33d721f998ca36 |
|---|
| Source note | uspto-grants-2015_11 |
|---|
