3-Pentanol → HCID 67400135, compound

HRID 711786Notes

Reaction equation

HRID 711786 reaction equation
[CH3:1][CH2:2][CH:3]([OH:6])[CH2:4][CH3:5].[N+]([C:10]1[CH:17]=[CH:16][CH:15]=[C:14]([N+:18]([O-:20])=[O:19])[C:11]=1[C:12]#[N:13])([O-])=O>>[N+:18]([C:14]1[CH:15]=[CH:16][CH:17]=[C:10]([O:6][CH:3]([CH2:4][CH3:5])[CH2:2][CH3:1])[C:11]=1[C:12]#[N:13])([O-:20])=[O:19]

Participants

3

Reactant 2

HCID 114283-PentanolHCID 520718Dinitrobenzonitrile

Product 1

HCID 67400135HCID 67400135, compoundYield 86.5%

Procedure

Prepared as in Example 111c from pentan-3-ol and 2,6-dinitrobenzonitrile in 86.5% yield. 1H NMR (400 MHz, DMSO-d6) δ 0.94 (t, J=7.6 Hz, 6H), 1.70 (m, 4H), 4.62 (m, 1H), 7.78 (dd, J=7.2, 2.4 Hz, 1H), 7.88 (m, 2H).

Sources & evidence

ORD record
ord-2894cfd4686a4ed0ac8c844231839cc3
Source dataset
uspto-grants-2015_11
Patent number
US09181276B2

Reaction notes

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