Selenium Dioxide → HCID 21896816, compound

HRID 719171Notes

Reaction equation

HRID 719171 reaction equation
[N:1]([C:4]1[CH:13]=[CH:12][CH:11]=[C:10]2[C:5]=1[CH2:6][CH2:7][CH2:8][C:9]2=[O:14])=[N+:2]=[N-:3].[Se](=O)=[O:16]>>[N:1]([C:4]1[CH:13]=[CH:12][CH:11]=[C:10]2[C:5]=1[CH:6]=[CH:7][C:8](=[O:16])[C:9]2=[O:14])=[N+:2]=[N-:3]

Participants

3

Reactant 2

HCID 24007Selenium DioxideHCID 218968435-Azido-3,4-dihydro-1(2H)-naphthalenone

Product 1

HCID 21896816HCID 21896816, compound

Procedure

Treatment of 5-azido-1-tetralone with selenium dioxide as described in Reference Example 1A yielded 5-azido-[1,2]naphthoquinone which was coupled with 2,3-diamino-benzoic acid, diacetate salt, as described in Reference Example 1A to yield the title compound.

Sources & evidence

ORD record
ord-45623d8afdcf4c2aa00862356849b694
Source dataset
uspto-grants-2006_11
Patent number
US07132419B2

Reaction notes

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