HuagongsheHuagongshe Chemistry Print Report · For research reference only
Azobisisobutyronitrile → HCID 58610590, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | N-bromobutanimide | HCID 67184 | — |
| Reactant | Ethyl 2'-methyl[1,1'-biphenyl]-3-carboxylate | HCID 12853045 | — |
| Reactant | 4'-Bromomethyl-biphenyl-3-carboxylic acid ethyl ester | HCID 21464255 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | HCID 58610590 | HCID 58610590 | — |
Reaction Steps
2′-Bromomethyl-biphenyl-3-carboxylic acid ethyl ester was synthesized as described for 4′-bromomethyl-biphenyl-3-carboxylic acid ethyl ester. 2′-Methyl-biphenyl-3-carboxylic acid ethyl ester (8.3 g, 34.54 mmol, 1 eq.) in carbon tetrachloride was treated with N-bromosuccinimide (7.38 g, 41.45 mmol, 1.2 eq.) and 2,2′-azobisisobutyronitrile (0.28 g, 1.73 mmol, 5 mol %). When complete, the reaction was worked up as described leaving an orange oil.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07132456B2 |
| Source dataset | uspto-grants-2006_11 |
| ORD ID | ord-93a2a49a9d544b53b0a780eed22a98f2 |
| Source note | uspto-grants-2006_11 |