HRID72081

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7730

Benzene, 1-bromo-4-methoxy-

C7H7BrO

HCID201262

Benzeneboronic acid, p-methoxy-

C7H9BO3

PRODUCTS

生成物

HCID16484

1,1'-Biphenyl, 4,4'-dimethoxy-

C14H14O2

收率 87%

PROCEDURE

实验过程

From 4-methoxy-bromobenzene and 4-methoxyphenyl boronic acid, yield 87%; mp 178-180° C. (lit.,1 179-180° C.); IR: 1599, 1493, 1466 and 1290; 1H NMR (400 MHz; CDCl3): 7.47 (4H, d, J 8.7), 6.96 (4H, d, J 8) and 3.84 (6H, s); 13C NMR (CDCl3): 159.1, 133.9, 128.1, 114.5 and 55.7; m/z (EI) 214 (100%, M+), 171 (70), 128 (50) and 69 (40)(Found: M+, 214.099. C14H14O2 requires M, 214.099).

WORKUP

后处理

custommp 178-180° C. (lit.,1 179-180° C.)