HRID72242

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID21916591

未命名化合物

结构：COC(=O)c1sc(C(O[SiH2]C(C)(C)C)(c2ccccc2)c2ccccc2)cc1N=CN(C)C

HCID131731827

未命名化合物

PRODUCTS

生成物

结构：CN(C)C1CCN(c2ccc(-n3cnc4cc(C(O[SiH2]C(C)(C)C)(c5ccccc5)c5ccccc5)sc4c3=O)cc2)C1

HCID131731826

未命名化合物

PROCEDURE

实验过程

5-(tert-Butyl-diphenyl-silanyloxymethyl)-3-(dimethylamino-methyleneamino)-thiophene-2-carboxylic acid methyl ester was reacted with [1-(4-Amino-phenyl)-pyrrolidin-3-yl]-dimethyl-amine by method A1. The product with the molecular weight of 608.87 (C35H40N4O2SSi) was obtained in this way; MS (ESI): 609 (M+H+).

WORKUP

后处理

customThe product with the molecular weight of 608.87 (C35H40N4O2SSi) was obtained in this way

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-00ebf7734d8f40c79d0e8437fbdbe257
来源数据集: uspto-grants-2014_09
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08828991B2
来源说明: uspto-grants-2014_09

反应 SMILES

CO[C:3]([C:5]1[S:6][C:7]([C:15]([C:28]2[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=2)([C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[O:16][SiH2:17][C:18]([CH3:21])([CH3:20])[CH3:19])=[CH:8][C:9]=1[N:10]=[CH:11][N:12](C)[CH3:13])=[O:4].NC1[CH:40]=[CH:39][C:38]([N:41]2[CH2:45][CH2:44][CH:43]([N:46]([CH3:48])[CH3:47])[CH2:42]2)=[CH:37][CH:36]=1>>[C:18]([SiH2:17][O:16][C:15]([C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][CH:29]=1)([C:22]1[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1)[C:7]1[S:6][C:5]2[C:3](=[O:4])[N:12]([C:13]3[CH:40]=[CH:39][C:38]([N:41]4[CH2:45][CH2:44][CH:43]([N:46]([CH3:48])[CH3:47])[CH2:42]4)=[CH:37][CH:36]=3)[CH:11]=[N:10][C:9]=2[CH:8]=1)([CH3:19])([CH3:21])[CH3:20]