HCID 19708278, compound → HCID 86751874, compound

HRID 725671Notes

Reaction equation

HRID 725671 reaction equation
[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][O:12][C:13]1[CH:18]=[CH:17][C:16]([O:19][C:20]([C:22]2[CH:30]=[CH:29][C:28]([C:31]([O:33][C:34]3[CH:39]=[CH:38][C:37]([O:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][O:47][C:48](=[O:51])[CH:49]=[CH2:50])=[CH:36][CH:35]=3)=[O:32])=[CH:27][C:23]=2[C:24]([OH:26])=[O:25])=[O:21])=[CH:15][CH:14]=1)(=[O:4])[CH:2]=[CH2:3].[N+:52]([C:55]1[CH:60]=[CH:59][C:58]([N:61]=[N:62][C:63]2[CH:81]=[CH:80][C:66]([C:67]([O:69][C:70]3[CH:79]=[CH:78][C:73]([O:74][CH:75](O)[CH3:76])=[CH:72][CH:71]=3)=[O:68])=[CH:65][CH:64]=2)=[CH:57][CH:56]=1)([O-:54])=[O:53]>CN(C)C1C=CN=CC=1.ClCCl>[C:1]([O:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][O:12][C:13]1[CH:14]=[CH:15][C:16]([O:19][C:20]([C:22]2[CH:30]=[CH:29][C:28]([C:31]([O:33][C:34]3[CH:35]=[CH:36][C:37]([O:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][O:47][C:48](=[O:51])[CH:49]=[CH2:50])=[CH:38][CH:39]=3)=[O:32])=[CH:27][C:23]=2[C:24]([O:26][CH2:76][CH2:75][O:74][C:73]2[CH:78]=[CH:79][C:70]([O:69][C:67](=[O:68])[C:66]3[CH:80]=[CH:81][C:63]([N:62]=[N:61][C:58]4[CH:59]=[CH:60][C:55]([N+:52]([O-:54])=[O:53])=[CH:56][CH:57]=4)=[CH:64][CH:65]=3)=[CH:71][CH:72]=2)=[O:25])=[O:21])=[CH:17][CH:18]=1)(=[O:4])[CH:2]=[CH2:3]

Participants

5

Reactant 2

HCID 19708278HCID 19708278, compoundHCID 54071153HCID 54071153, compound

Product 1

HCID 86751874HCID 86751874, compound

Reagents, catalysts & solvents 2

HCID 142844-(Dimethylamino)pyridineCatalystHCID 6344DichloromethaneSolvent

Procedure

A solution of 0.6 g of 2,5-bis[4-(6-acryloyloxyhexyloxy)phenylcarboxy]benzoic acid, 0.4 g of (4-[4-(4-nitrophenylazo)benzoyloxy]phenoxy)ethanol and 0.04 g of 4-dimethylaminopyridine is reacted with 0.2 g of N,N'-dicyclohexyldicarbodiimide and 20 ml of dichloromethane in an analogous manner to Example 1 to give (4-[4-(4-nitrophenylazo)benzoyloxy]phenoxy)ethyl 2,5-bis[4-(6-acryloyloxyhexyloxy)phenylcarboxy]benzoate.

Sources & evidence

ORD record
ord-56e008645631495aa11fdd640cd7c1cf
Source dataset
uspto-grants-1998_01
Patent number
US05707544

Reaction notes

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