HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzene → [1,1'-Biphenyl]-2-carbonyl chloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzene | HCID 241 | — |
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | Oxalyl chloride | HCID 65578 | — |
| Reactant | o-Phenylbenzoic acid | HCID 70357 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | [1,1'-Biphenyl]-2-carbonyl chloride | HCID 12563768 | — |
Reaction Steps
o-Phenylbenzoic acid (163 mg) was dissolved in 5 ml of methylene chloride, a catalytically effective amount of N,N-dimethylformamide was added dropwise, and 0.165 ml of oxalyl chloride was added dropwise. After 3 hours of stirring at room temperature, benzene was added and the solvent was evaporated to obtain o-phenylbenzoic acid chloride.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05710150 |
| Source dataset | uspto-grants-1998_01 |
| ORD ID | ord-797bf1e57b8046ebb97ba8ccb29a2e67 |
| Source note | uspto-grants-1998_01 |