Hydrogen Peroxide → HCID 86751977, compound

HRID 727227Notes

Reaction equation

HRID 727227 reaction equation
[OH:1]O.[CH3:3][C:4]1[CH:9]=[C:8]([CH3:10])[N:7]=[C:6]([NH:11][C:12]([C:14]2[CH:19]=[N:18][CH:17]=[CH:16][N:15]=2)=[O:13])[CH:5]=1>C(O)(=O)C>[CH3:3][C:4]1[CH:9]=[C:8]([CH3:10])[N:7]=[C:6]([NH+:11]([O-:1])[C:12]([C:14]2[CH:19]=[N:18][CH:17]=[CH:16][N:15]=2)=[O:13])[CH:5]=1

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 1225859HCID 1225859, compound

Product 1

HCID 86751977HCID 86751977, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Conditions

Temperature
70 °C

Procedure

A solution of 10 ml of glacial acetic acid and 0.7 ml of aqueous hydrogen peroxide solution (35%) are added, with stirring, to 1 g of compound obtained in Example 21. The reaction medium is heated at 70° C. for 7 h and then concentrated under reduced pressure and at low temperature.

Workup

  1. concentrationconcentrated under reduced pressure and at low temperature

Sources & evidence

ORD record
ord-6ba6f2a0b0074acba258d237ffcc8d86
Source dataset
uspto-grants-1998_01
Patent number
US05712294

Reaction notes

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