Triethylamine → HCID 14989154, compound

HRID 728397Notes

Reaction equation

HRID 728397 reaction equation
[CH3:1][C:2]([C:5]1[CH:10]=[C:9]([SH:11])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])[CH3:3].Cl[CH2:18][CH2:19][CH2:20][C:21](=[O:23])[CH3:22].C(N(CC)CC)C>C(OCC)C>[CH3:4][C:2]([C:5]1[CH:10]=[C:9]([S:11][CH2:18][CH2:19][CH2:20][C:21](=[O:23])[CH3:22])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:1])[CH3:3]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 703702,6-Di-tert-butyl-4-mercaptophenolHCID 799932-Pentanone, 5-chloro-

Product 1

HCID 14989154HCID 14989154, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

The thio of Example 2 (5.0 g, 0.021 M) was reacted with 5-chloro-2-pentanone (2.87 ml) and triethylamine (3.0 ml) in ethyl ether (50 ml) by the method of Example 8 to give the title compound, m.p. ca. 65-67° C.

Sources & evidence

ORD record
ord-954c54a4218e40ef8ad73d00f9dbfd65
Source dataset
uspto-grants-1991_09
Patent number
US05047593

Reaction notes

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