Triethylamine → HCID 14989155, compound

HRID 728398Notes

Reaction equation

HRID 728398 reaction equation
[CH3:1][C:2]([C:5]1[CH:10]=[C:9]([SH:11])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])[CH3:3].[CH:17]([C:20]([CH:22]=[CH2:23])=[O:21])([CH3:19])[CH3:18].C(N(CC)CC)C>CO>[CH3:4][C:2]([C:5]1[CH:10]=[C:9]([S:11][CH2:23][CH2:22][C:20](=[O:21])[CH:17]([CH3:19])[CH3:18])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:1])[CH3:3]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 703702,6-Di-tert-butyl-4-mercaptophenolHCID 741521-Penten-3-one, 4-methyl-

Product 1

HCID 14989155HCID 14989155, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

The thiol of Example 2 (4.76 g, 0.02 mole) was reacted with isopropylvinyl ketone (3.6 g) and triethylamine (3 ml) in methanol (50 ml) by the method of Example 3 to give the title compound, m.p. ca. 50-53° C.

Sources & evidence

ORD record
ord-085aec85e32240c5ab6c543786e87f39
Source dataset
uspto-grants-1991_09
Patent number
US05047593

Reaction notes

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